Bar-tender with a Shotgun
Scavenger / Scrounger
School teacher (someone has to educate the masses to get civilization restarted)
Librarian (someone should be organizing the records)
Slaver (for an eviler campaign)
Explorer (roams around looking for settlements or ruins)
Tradesman (blacksmith, leather-worker, mason, etc.) _________________ "Got a problem? I've got the solution: Rocket Launcher."
"Not against a Servitor."
"... We're all gonna die."
Weird scientist also works fairly well. You'll probably want to trim the overall powerset to what strikes you as thematically appropriate, but Fallout's variety of Sci-fi is soft enough that this works fine.
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